Peroxide vs. Non-peroxide Tooth Whitening (2024)

There are various methods and procedures (in-office bleaching, home kits, whitening strips, DIY remedies, etc.), but also different kinds of tooth whitening products available in the market.Most of the current methods can be split into two categories: those that use peroxide as the active ingredient and those that don’t. This article aims at shedding some light on the significant differences between all the options and clearing up some common misunderstandings.

Peroxide-based whitening:

There are two types of peroxide-based teeth whitening gels: hydrogen peroxide (for chair-side use) and carbamide peroxide (for home use).

Hydrogen peroxide

When it comes to teeth whitening, hydrogen peroxide is the main and strongest active ingredient used by dentists worldwide. It breaks down into oxygen and water and it starts working right after applying it to the teeth, yielding dramatic results in less than an hour.

Teeth have micro-fine pores, making the enamel a semi-permable layer. When hydrogen peroxide decomposes, oxygen penetrates the enamel through these pores to reach the discolored molecules (residue from coffee, tobacco, foods, beverages, etc.) inside the tooth. This process is excellent in terms of whitening effect, but it has a significant adverse effecttooth sensitivity. When the pores of the enamel are open, teeth become more susceptible to dehydration and demineralization, which leads to tooth sensitivity.

In the United States and many other countries dentists offer whitening treatments with hydrogen peroxide concentrations of up to 40%.

Carbamide peroxide

Carbamide peroxide, also called urea peroxide, is made from hydrogen peroxide. To make carbamide, a urea molecule is added to each hydrogen molecule to make the gel much more stable. It was designed for over-the-counter teeth whitening products since hydrogen peroxide tends to have a short shelf-life, especially in higher concentrations.

During the whitening process carbamide breaks down into hydrogen peroxide, but it takes about 30-60 minutes for that process to start. Since this type of whitening takes longer, it’s most suitable for home whitening treatment and perfect for touch-up pens and take-home kits.

There is a 3:1 relationship between these. In other words, 35% CP is equivalent to around 12% HP, 22% CP is equivalent to 7% HP and 16% CP is equivalent to 6% HP.

Because abuse or improper use of peroxide can have negative effects on the teeth, the European Commission limited the concentration of peroxide in cosmetic products in 2011. Thus, according to the current legislation non-dental professionals in Europe can use only up to 0.1% hydrogen peroxide (present or released) and dentists can use only up to 6% hydrogen peroxide (or its equivalent 16% carbamide peroxide).

Non-peroxide based whitening

Due to the new legislation on peroxide content in cosmetic products, ‘peroxide-free’ teeth whitening has experienced a remarkable growth over the last few years, also beyond EU borders. The most common active ingredients in non-peroxide based whitening products are sodium bicarbonate, commonly known as baking soda, and sodium percarbonate.

Sodium bicarbonate:

As a mild abrasive, sodium bicarbonate helps remove superficial stains from teeth. Also, it has a cleansing action by loosening food debris, it neutralizes the production of acid in the mouth and it prevents bacteria overgrowth. However, if not used in the correct proportion – especially with plain baking soda – it can eventually erode the enamel and lead to tooth decay.

Sodium percarbonate:

Sodium percarbonate is a safe and environmentally-friendly agent that has not only cleansing and whitening, but also antibacterial properties. When it comes into contact with saliva it decomposes into natural soda ash and peroxide (oxygen and water), though products sold in the European Union do not release more than 0.1% hydrogen peroxide, in compliance with the EU Cosmetics Directive

Sodium percabonate is being increasingly used by dentists to bleach dead teeth from the inside outa process also know as internal bleaching. With this technique, instead of applying the whitening agent on the surface of the teeth to penetrate to the areas where discoloration occurs, the gel goes right to the tooth’s interior, which is a highly sensitive area. As sodium percarbonate gives good results with very little to no side effects, it’s the ideal whitening agent for such purpose.

In terms of efficacy it’s important to understand that these products cannot remove deep discoloration inside the tooth, like peroxide does. Nonetheless and depending on the brand and the formula, they can achieve nice results, especially sodium percarbonate.As a matter of fact, Beaming White’s sodium percarbonate gels have been testedon their efficacy by independent testing bodies such as Eurofins and were found to give an average bleaching efficacy of 3.6 shades, with testers yielding up to 7 shades whiter after 1 single treatment.

As far as safety is concerned, non-peroxide based gels will typically not cause any tooth sensitivity or gum irritation, so they are ideal for people with sensitive teeth or for those who are afraid of using products containing peroxide.

Peroxide vs. Non-peroxide Tooth Whitening (2024)

FAQs

Peroxide vs. Non-peroxide Tooth Whitening? ›

In general, there is low evidence regarding the effectiveness and safety of OTC teeth-whitening agents [2,33]. A recent meta-analysis compared several laboratory studies and demonstrated that non-peroxide bleaching agents were less effective compared to peroxide-based bleaching agents [34].

Is non-peroxide teeth whitening effective? ›

Non-Peroxide Teeth Whitening vs Natural Remedies

DIY whitening solutions, such as baking soda or lemon juice, can be harsh and harmful to enamel. Non-peroxide products are designed to be gentle but effective, providing a safer alternative to these homemade remedies.

Is it good to use hydrogen peroxide to whiten teeth? ›

According to studies, hydrogen peroxide can damage your teeth when in teeth whitening products or with at-home applications. Under certain circ*mstances, the damage can be heightened: Using a highly concentrated solution. Allowing the solution to contact the teeth for a prolonged duration.

How does peroxide free teeth whitening work? ›

Peroxide-free teeth whitening

Some of the most common non-peroxide ingredients used in whitening toothpastes, strips and gels include sodium bicarbonate (bicarb soda) and natural alternatives such as charcoal. Because they are abrasive, these ingredients can help to remove surface stains and brighten teeth.

How do non-peroxide whitening strips work? ›

The most common active ingredients in non-peroxide based whitening products are sodium bicarbonate, commonly known as baking soda, and sodium percarbonate. Sodium bicarbonate: As a mild abrasive, sodium bicarbonate helps remove superficial stains from teeth.

How do you get rid of yellow teeth without hydrogen peroxide? ›

Rub banana, orange, or lemon peels:

To perform this “trick,” take a banana, orange, or lemon peel and gently rub it on your teeth. Keep rubbing it for about 2 minutes, then thoroughly wash your mouth and brush your teeth. The peels of these fruits contain citric acid, which theoretically helps in teeth whitening.

Do dentists recommend hydrogen peroxide? ›

Hydrogen Peroxide as a Gum Disease Treatment

This more severe form of gum disease can cause your teeth to loosen or even fall out. Because it can kill harmful bacteria and break up plaque, dental professionals have been using hydrogen peroxide since the early 1900s to prevent and treat periodontitis.

Does hydrogen peroxide remove tartar? ›

No, hydrogen peroxide doesn't dissolve tartar, but it can help remove the plaque that hardens into tartar.

What happens if you use hydrogen peroxide on your teeth everyday? ›

That's because hydrogen peroxide is very reactive. Using it in high concentrations or for a long period of time may damage your gums and teeth. If you're considering using hydrogen peroxide regularly, only use it in low concentrations.

What is a good alternative to hydrogen peroxide for teeth? ›

PAP is a non-peroxide-based solution that has shown to be just as effective as peroxide-based products. This organic peroxy acid is used as a bleaching activator in laundry detergents, and thus the idea to use it as a teeth whitener was born.

What is the best teeth whitening without peroxide? ›

Lumineux Teeth Whitening Strips 21 Treatments – Peroxide Free - Enamel Safe for Whiter Teeth - Whitening Without The Sensitivity - Dentist Formulated and Certified Non-Toxic - Sensitivity Free. Amazon's Choice highlights highly rated, well-priced products available to ship immediately.

How long is hydrogen peroxide active on teeth whitening? ›

Hydrogen peroxide is inherently unstable and will break down immediately once you place the whitening trays in your mouth The majority of the peroxide will be spent within the first 20 minutes of wear, but to experience the full effect of the gel, we recommend at least 1 to 1.5 hours of wear time.

Is non-peroxide teeth whitening safe? ›

12% of PAP in whitening gel used with whitening tray for teeth bleaching is as effective as 8% of hydrogen peroxide [2] but does not cause any harm and is not toxic in regular use.

What are the cons of using hydrogen peroxide to whiten teeth? ›

Risks of Hydrogen Peroxide

The website Dentaly.Org stated the following "The dilution of hydrogen peroxide considered safe to use is 3%. Any higher, and you could risk damaging your enamel for good. Even then, using it for prolonged periods of time can still cause damage.

Are Crest White Strips just hydrogen peroxide? ›

The strips are made of a plastic material and are coated with adhesive and hydrogen peroxide or carbamide peroxide whitening gel.

Do over the counter teeth whiteners really work? ›

Then, over-the-counter whitening agents can work effectively. But because it's not dentist-monitored, many of them don't do anything. For instance, a mouthwash containing a whitening agent such as hydrogen peroxide probably is not going to be very effective.

Will 0.1 hydrogen peroxide whiten teeth? ›

The acidic nature of these gels can also be harmful. In the UK and Europe, tooth whitening products sold over the counter must contain or release up to 0.1% hydrogen peroxide, this strength has little impact on whitening teeth.

Can you whiten your teeth without damaging them? ›

Many at-home tooth whitening methods have the potential to cause harm but your dentist can give you trays and gel containing carbamide peroxide. The trays are custom-fitted to protect your gums and your dentist makes sure that your mouth is healthy enough before you get started.

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